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UID:20250817T035055EDT-8976ks8pwB@132.216.98.100
DTSTAMP:20250817T075055Z
DESCRIPTION:Carbon dioxide is one of the most attractive renewable C1 resou
 rces\, which has many practical advantages such as abundance\, economic ef
 ficiency\, and lack of toxicity. The favorable nature as a carbon source i
 s\, however\, inextricably linked to its inherent inertness. Here we repor
 t a new strategy to circumvent thermodynamic and kinetic barriers for copo
 lymerizations of carbon dioxide and olefins by using a meta-stable lactone
  intermediate\, 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one\, which is f
 ormed by the palladium-catalyzed condensation of carbon dioxide and 1\,3-b
 utadiene. Subsequent free radical polymerization of the lactone intermedia
 te afforded high-molecular-weight polymers with a carbon dioxide content o
 f 33 mol% (29 wt%). 1\n\nOur latest results in direct and selective hydrog
 enolysis of sp2 C–OH bonds in arenols and O–CH3 bonds in aryl methyl ether
 s by hydroxycyclopentadienyl dihydridoiridium catalysts will be also prese
 nted\, implying their potential application for mass production of arenes 
 from lignin or its degraded components.2\n\nmas1. Nakano\, R.\; Ito\, S.\;
  Nozaki\, K. Nature Chem. 2014\, 6\, 325-331\n	2. Kusumoto\,S.\;  Nozaki\, 
 K. Nature Commun. 2015\, 6\, 6296.\n\n \n
DTSTART:20170314T170000Z
DTEND:20170314T181500Z
LOCATION:Room 10\, Maass Chemistry Building\, CA\, QC\, Montreal\, H3A 0B8\
 , 801 rue Sherbrooke Ouest
SUMMARY:CCVC Seminar: Dr. Kyoko Nozaki - Development of New Catalytic React
 ions toward Utilization of Renewable Resources
URL:/chemistry/channels/event/ccvc-seminar-dr-kyoko-no
 zaki-development-new-catalytic-reactions-toward-utilization-renewable-2665
 54
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