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UID:20251119T133056EST-2372TVNMT6@132.216.98.100
DTSTAMP:20251119T183056Z
DESCRIPTION:Our group's research is mainly focusing on the functionalizatio
 n of unactivated C(sp3)-H bonds under\n	catalysis by palladium(0) complexes
 . A first strategy\, which we have been pursuing for the past 15 years\,\n
 	relies on intramolecular C-H activation and allows for the creation of a v
 ariety of interesting ring systems\n	from simple precursors.\n\n\n	More rece
 ntly\, we have investigated a different strategy for the intermolecular fu
 nctionalization of remote\n	C(sp3)-H bonds via a Pd 'chain-walk' mechanism.
  We showed that the site-selectivity of the cross-coupling\n	on the alkyl c
 hain can be controlled by the ligand\, with bulky phosphines giving rise t
 o the direct coupling\n	product whereas homemade conformationally flexible 
 ligands favor the migratory coupling product.\n\nThis lecture will present
  this concept in the context of two cross-couplings: the arylation of este
 r enolates\n	and the Negishi coupling.\n
DTSTART:20180621T170000Z
DTEND:20180621T183000Z
LOCATION:Room 10\, Maass Chemistry Building\, CA\, QC\, Montreal\, H3A 0B8\
 , 801 rue Sherbrooke Ouest
SUMMARY:CCVC Seminar: Olivier Beaudoin - Direct vs. migratory Pd-catalyzed 
 cross-coupling
URL:/chemistry/channels/event/ccvc-seminar-olivier-bea
 udoin-direct-vs-migratory-pd-catalyzed-cross-coupling-287298
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